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Nealeigh Mitchell | Excelle

Brad Pitt : Angelina Jolie

THE FROLIC: How do you relax after a tense day of car chases and shootings on a movie set? Why, by cuddling with your costar in your trailer, of course. OK, that’s may not be exactly how two of the world’s most beautiful people hooked up, but Angelina Jolie admits she fell for then-married Brad Pitt while on the set of Mr. and Mrs. Smith. Their onscreen chemistry kept us on the edge of our seats so we weren’t too shocked to hear they’d shacked up after the cameras stopped rolling. Jolie claims she kept her distance until Pitt divorced his then-wife of five years, Jennifer Aniston. Pitt just happened to file those papers that same year. Hmmm.

THE FALLOUT: Tabloid magazines owe a good portion of their revenue to steering the Angie and Brad breakup bandwagon. The gossip mill churns out a separation story every other week but the pair — who’ve never been officially married — are seemingly still going strong. Not just a pair of pretty faces, the charitable couple are attached to several humanitarian causes. In 2006, they established the Jolie-Pitt foundation to aid in global causes. Most recently, the foundation donated $1 million to Doctors Without Borders to help victims of the Haiti earthquake.

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